Pyar Vali Love Story presents two parallel stories. The first one is between a Garage owner Pashyabhai in a chawl and a street-smart and blunt girl Nandini , living in the chawl. When their marriage takes place, Pashyabhai's younger brother Amar arrives in the chawl and then begins another love story between Amar and Aliya, a muslim girl( Sai Tamhankar) living in the neighbourhood. Aliya's brother Kadar (Upendra Limaye) who is also good friend of Pashyabhai, fixes the marriage of his sister with Inspector Alam (Chinmay Mandlekar). When Kadar comes to know about his sister's relationship with Amar, he warns him and even beats him. In the meanwhile, communal riots break out and Inspector Alam is killed. Kadar suspects Amar and vows to take the revenge. Amar and Aliya who are intensely in love, manage to run away from the scene.
Nandini (Sai Tamhankar) is someone who is a staunch believer in love marriages but following her father's orders, she gets married to Siddharth (Swwapnil Joshi) who is coping with heartbreak. Eight years later, Siddharth and Nandini are leading happy lives in Mumbai with their daughter. Kamlakar Bhanushali (Girish Oak), a politician who has some connection with Siddharth's past, comes to Siddharth's workplace and makes a proposal to him. He tells Siddharth that he's ready to fund Siddharth's work plant with Rs 25 crore provided he gets rid of Nandini. Turns out, Siddharth used to be in a relationship with Bhanushali's daughter Bhairavi (Tejaswini Pandit).How this situation resolves forms the crux of the story.
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